オーラルセッション
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1B-O2-1720 PDF
熱分解GC-光イオン化-飛行時間型高分解能質量分析とKMDプロット法による高分子有機半導体ポリ（3-ヘキシルチオフェン）の熱分解生成物解析
Py-GC/MS has been applied to structural analysis of commodity, engineering, and high-performance plastics. On the other hand, the application of Py-GC/MS to structural analysis of polymer semiconductors having rigid π-conjugated structures in their main chain has not been well examined. In this study, we performed structural analysis of poly(3-hexylthiophene) by Py-GC/MS technique. Here we used a GC/MS instrument with a high-resolution time-of-flight-mass spectrometer equipped with a photo-ionization (PI) source. Since PI is a soft ionization method, we could find the pyrolyzed compounds derived from π-conjugated main chain. In addition, we found that the pyrolyzed compounds can be categorized in several groups by Kendrick Mass Defect (KMD) analysis.