The Mass Spectrometry society of Japan - The 68th Annual Conference on Mass Spectrometry, Japan

Abstract

Oral Sessions

Day 3, June 24(Fri.) 15:20-15:40 Room C (411 and 412)

New insights of complementary fragment ions generated by high-resolution EI/FI MS of methylstearate

(1Yokohama City Univ., 2JEOL)
oMitsuo Takayama1, Masaaki Ubukata2, Kenji Nagatomo2

Fragmentation of methylstearate has been examined by introducing a method for separation and classification of fragment ions into homologous series observed in high-resolution EI and FI mass spectra. The fragment ions were classified into three homologous series, i.e., aliphatic hydrocarbon, acylium and methylester. Original EI/FI mass spectra were reconstructed from the homologous series ions, and the formation of complementary fragment ions was analyzed on the basis of the reconstructed EI/FI mass spectra.